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Rigid, yet flexible: formation of unprecedented silver MB-DIPY dimers with orthogonal chromophore geometry.
Dalton Transactions ( IF 3.5 ) Pub Date : 2020-04-28 , DOI: 10.1039/d0dt00927j Yuriy V Zatsikha 1 , Liliya I Shamova 1 , Tanner S Blesener 1 , David E Herbert 1 , Victor N Nemykin 1
Dalton Transactions ( IF 3.5 ) Pub Date : 2020-04-28 , DOI: 10.1039/d0dt00927j Yuriy V Zatsikha 1 , Liliya I Shamova 1 , Tanner S Blesener 1 , David E Herbert 1 , Victor N Nemykin 1
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The reaction between MB-DIPY sodium salts and Ag(i) ions results in the formation of unprecedented MB-DIPY2Ag2 dimers in both solution and the solid state. These dimers have a short Ag-Ag contact (∼2.9 Å) and orthogonal twist in each of the MB-DIPY chromophores. The electronic structure of the unique dimers was probed by spectroscopic and theoretical methods.
中文翻译：
刚性而又灵活：形成了前所未有的具有正交发色团几何形状的MB-DIPY银二聚体。
MB-DIPY钠盐与Ag（i）离子之间的反应导致溶液和固态均形成了前所未有的MB-DIPY2Ag2二聚体。这些二聚体具有短的Ag-Ag接触（〜2.9Å），并且在每个MB-DIPY发色团中都具有正交扭曲。独特的二聚体的电子结构通过光谱和理论方法进行了研究。
更新日期：2020-03-13
中文翻译：
刚性而又灵活：形成了前所未有的具有正交发色团几何形状的MB-DIPY银二聚体。
MB-DIPY钠盐与Ag（i）离子之间的反应导致溶液和固态均形成了前所未有的MB-DIPY2Ag2二聚体。这些二聚体具有短的Ag-Ag接触（〜2.9Å），并且在每个MB-DIPY发色团中都具有正交扭曲。独特的二聚体的电子结构通过光谱和理论方法进行了研究。
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