Two novel OH-functionalized intrinsically microporous polymers were successfully synthesized from a tert-butyldimethylsilyl (TBS) protected 1,1′-binaphthalene-diamine monomer (NH₂-BINOL-TBS). Interestingly, the polymerization and the removal of the TBS to form OH group happened at the same time. Polymers with 30% (PIM-HNTB-30) and 60% (PIM-HNTB-60) OH concentration were obtained by controlling the reaction time of 3.5 and 12 h, and confirmed by nuclear magnetic resonance spectroscopy (NMR). PIM-HNTB-30 exhibited higher Brunauer-Emmett-Teller (BET) surface area (432 vs 153 m² g^-1) and thermal stabilities (420 vs 385 °C) than PIM-HNTB-60. Both membranes showed modest gas permeabilities and selectivities, and PIM-HNTB-60 exhibited a relatively higher performance. After long-term aging or thermally annealed above glass transition temperature (T_g), both polymers exhibited a decreased permeabilities combined with a selectivity increase, and the 350 °C treated PIM-HNTB-60 exhibited O₂ permeability of 89 Barrer and O₂/N₂ selectivity of 4.47. In all, the OH functionalization provided a good way to enhance the gas separation performance.

从叔丁基二甲基甲硅烷基（TBS）保护的1,1'-联萘-二胺单体（NH ₂ -BINOL-TBS）成功合成了两种新型的OH-官能化的本质上微孔聚合物。有趣的是，聚合和除去TBS形成OH基是同时发生的。通过控制3.5和12小时的反应时间，获得具有30％（PIM-HNTB-30）和60％（PIM-HNTB-60）OH浓度的聚合物，并通过核磁共振波谱法（NMR）确认。PIM-HNTB-30表现出更高的Brunauer-Emmett-Teller（BET）表面积（432 vs 153 m ²  g ^-1）和热稳定性（420 vs385°C）。两种膜均显示出适度的气体渗透性和选择性，而PIM-HNTB-60表现出相对较高的性能。经过长期老化或在高于玻璃化转变温度（T _g）的温度下进行热退火后，两种聚合物的渗透率均降低，而选择性则有所提高，经350°C处理的PIM-HNTB-60的O ₂渗透率为89 Barrer和O ₂ / N _2的选择性为4.47。总之，OH官能化提供了一种增强气体分离性能的好方法。