In the present work, the mechanochemical synthesis of polyboronphenylsiloxanes was carried out. Boron difluoride acetylacetonate and polyphenylsilsesquioxane were used as starting reagents. The products of the syntheses were studied by IR and NMR spectroscopy, elemental and X-ray phase analysis, gel permeation chromatography and MALDI-TOF/TOF-MS. The composition of the obtained products was determined established. It is shown that the fluorine radical released as a result of mechanical activation, as well as air humidity, plays a major role in the formation of products.

中文翻译：

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聚硼苯基硅氧烷的机械化学合成

在本工作中，进行了聚硼苯基硅氧烷的机械化学合成。二氟化硼乙酰丙酮硼酸酯和聚苯基倍半硅氧烷用作起始试剂。通过IR和NMR光谱，元素和X射线相分析，凝胶渗透色谱法和MALDI-TOF / TOF-MS研究了合成的产物。确定所得产物的组成。已经表明，由于机械活化以及空气湿度而释放的氟自由基在产物的形成中起主要作用。