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Trapping of Difluorocarbene by Frustrated Lewis Pairs
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-03-11 , DOI: 10.1002/anie.202001354 Vladimir O. Smirnov 1 , Alexander D. Volodin 2 , Alexander A. Korlyukov 2, 3 , Alexander D. Dilman 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-03-11 , DOI: 10.1002/anie.202001354 Vladimir O. Smirnov 1 , Alexander D. Volodin 2 , Alexander A. Korlyukov 2, 3 , Alexander D. Dilman 1
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Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho‐position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.
中文翻译：
沮丧的路易斯对诱捕二氟卡宾
由位于邻位的二苯基膦基和硼基组成的沮丧的Lewis对可以捕获二氟卡宾，提供稳定的两性离子加合物。该反应可以在升高的温度下逆转以释放出二氟卡宾。
更新日期：2020-03-11
中文翻译：
沮丧的路易斯对诱捕二氟卡宾
由位于邻位的二苯基膦基和硼基组成的沮丧的Lewis对可以捕获二氟卡宾，提供稳定的两性离子加合物。该反应可以在升高的温度下逆转以释放出二氟卡宾。
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