Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties,Dalton Transactions

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Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties
Dalton Transactions ( IF 3.5 ) Pub Date : 2020/03/12 , DOI: 10.1039/d0dt00353k
Hui-Shu Lu _{1,

2,

3,

4,

5} , Wang-Kang Han _{1,

2,

3,

4,

5} , Xiaodong Yan _{1,

2,

3,

4,

5} , Ya-Xin Xu _{1,

2,

3,

4,

5} , Hai-Xia Zhang _{1,

2,

3,

4,

5} , Tao Li _{1,

2,

3,

4,

5} , Yu Gong _{1,

2,

3,

4,

5} , Qing-Tao Hu _{1,

2,

3,

4,

5} , Zhi-Guo Gu _{1,

2,

3,

4,

5}

Affiliation

Two Fe^II₈L₁₂ cubic metal–organic cages were constructed with semi-rigid ligands and they further self-assembled into supramolecular assemblies with three different porous cavities. The supramolecular assemblies showed synergistic adsorption of I₂ and TTF, and their solid state spin-crossover behaviors were influenced by the adsorbed guest molecules.

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