C–H Insertion Reactions of Donor/Donor Carbenes: Inception, Investigation, and Insights,Synlett

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C–H Insertion Reactions of Donor/Donor Carbenes: Inception, Investigation, and Insights
Synlett ( IF 1.7 ) Pub Date : 2020-03-10 , DOI: 10.1055/s-0039-1691738
Jared T Shaw ₁

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Insertion reactions of donor/donor carbenes have emerged from obscurity to become a versatile method for the synthesis of a variety of cyclic structures with excellent control of diastereo- and enantioselectivity. This Account describes the origin of this project as part of a natural product synthesis and the ensuing decade of reaction development that has resulted in new asymmetric methods as well as intriguing tangential observations.

中文翻译：

供体/供体卡宾的 C–H 插入反应：开始、调查和洞察

供体/供体卡宾的插入反应已经从默默无闻中脱颖而出，成为合成各种环状结构的通用方法，具有出色的非对映选择性和对映选择性。本报告将这个项目的起源描述为天然产物合成的一部分，以及随后十年的反应发展，这些发展导致了新的不对称方法以及有趣的切向观察。

更新日期：2020-03-10

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