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Surface Modification for Promoting Durable, Efficient, and Selective Electrocatalysts
ChemElectroChem ( IF 3.5 ) Pub Date : 2020-03-10 , DOI: 10.1002/celc.202000132
Quentin Lenne 1 , Yann R. Leroux 1 , Corinne Lagrost 1
Affiliation  

Intensive research into the design of catalysts involved in energy conversion and fuel cell technologies has allowed great progress in the field. However, durable, efficient and selective electrocatalytic systems for the activation of fuel molecules at the lowest cost are still needed. The most developed strategies consist of tailoring the shape, size and composition of metallic nanomaterials. Yet, deliberate surface modification of the catalysts should be considered as a promising alternative approach. The functionalization of metallic catalysts with organic ligands has been recently demonstrated to promote high catalytic activity. This Review focuses on the functionalization of metallic or alloy catalysts with organic ligands, showing the impact of the surface modification for different materials and different reactions. Hybrid systems based on this alternative strategy could contribute to the elaboration of cutting‐edge systems for electrocatalysis.

中文翻译:

表面改性以促进持久,高效和选择性的电催化剂

对涉及能量转换和燃料电池技术的催化剂设计的深入研究已使该领域取得了长足的进步。然而,仍然需要用于以最低成本活化燃料分子的耐用,有效和选择性的电催化系统。最发达的策略包括定制金属纳米材料的形状,尺寸和组成。但是,对催化剂进行有意的表面改性应被视为一种有前途的替代方法。最近已证明金属催化剂与有机配体的官能化可促进高催化活性。这篇综述着重于金属或合金催化剂与有机配体的功能化,显示了表面改性对不同材料和不同反应的影响。
更新日期:2020-03-10
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