Abstract In this work, firstly, [Zn2(bdc)2(dabco)]n as a metal organic framework (MOF) was synthesized via chemical routes. Finally, for improving electrochemical properties of the poly ortho aminophenol (POAP), we fabricated POAP/chitosan/MOF-1 films by electro- polymerization of POAP in the presence of Chitosan/MOF-1 to serve as the active electrode for electrochemical supercapacitor. The structural and valance state of the prepared samples was characterized by X-ray diffraction (XRD), and field emission scanning electron microscopy (FESEM). Different electrochemical methods including galvanostatic charge–discharge experiments, cyclic voltammetry and electrochemical impedance spectroscopy are carried out in order to investigate the performance of the system. This work introduces new most efficient materials for electrochemical redox capacitors with advantages including ease synthesis, high active surface area and stability in an aqueous electrolyte.

中文翻译：

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导电聚合物/壳聚糖生物聚合物/金属有机骨架的三元纳米复合材料：作为赝电容器有效电极材料的合成、表征和电化学性能

摘要 在这项工作中，首先通过化学途径合成了[Zn2(bdc)2(dabco)]n 作为金属有机骨架(MOF)。最后，为了提高聚邻氨基苯酚 (POAP) 的电化学性能，我们在壳聚糖/MOF-1 存在下通过电聚合 POAP 制备了 POAP/壳聚糖/MOF-1 薄膜，作为电化学超级电容器的活性电极。通过X射线衍射（XRD）和场发射扫描电子显微镜（FESEM）表征所制备样品的结构和价态。进行了不同的电化学方法，包括恒电流充放电实验、循环伏安法和电化学阻抗谱，以研究系统的性能。