当前位置: X-MOL 学术Tetrahedron › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Epoxidation of microalgal biomass-derived squalene with hydrogen peroxide using solid heterogeneous tungsten-based catalyst
Tetrahedron ( IF 2.1 ) Pub Date : 2020-03-09 , DOI: 10.1016/j.tet.2020.131109
Hidehisa Kawashima , Yuki Okuda , Masashi Kijima , Tadahiro Fujitani , Jun-Chul Choi

Squalene structurally resembles petroleum resources, and is efficiently produced by Aurantiochytrium mangrovei, a microalga, and could be used effectively as an alternative oil resource. An efficient heterogeneous catalyst system for the epoxidation of squalene was developed, comprising the heterogeneous catalyst [N(C6H13)4]3[PW4O8(O2)8] for the successful epoxidation of squalene with H2O2 in t-BuOH. The addition of the tetraalkylammonium salt [N(C6H13)4]Cl, and H2O2 as the oxidant allowed quantitative epoxidation of squalene.



中文翻译:

固体非均相钨基催化剂用过氧化氢对微藻类生物质角鲨烯进行环氧化

角鲨烯在结构上类似于石油资源,是由微藻类金红树有效生产的,可以有效地用作替代石油资源。开发了一种用于角鲨烯环氧化的高效多相催化剂体系,该体系包括用于成功将角鲨烯与H 2 O 2环氧化的多相催化剂[N(C 6 H 134 ] 3 [PW 4 O 8(O 28 ]。在t -BuOH中。四烷基铵盐[N(C 6 H 134的添加] Cl和作为氧化剂的H 2 O 2允许角鲨烯的定量环氧化。

更新日期:2020-03-10
down
wechat
bug