Serendipitous Formation of Semiconducting Semi-Nindigo Indigoid by the Degradation of Diindolopyrrole,The Journal of Organic Chemistry

当前位置： X-MOL 学术 › J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Serendipitous Formation of Semiconducting Semi-Nindigo Indigoid by the Degradation of Diindolopyrrole
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2020-03-19 , DOI: 10.1021/acs.joc.0c00054
Nathan Yee ₁ , Afshin Dadvand ₁ , Dmitrii F. Perepichka ₁

Affiliation

We report the serendipitous discovery and synthesis of an indigoid “semi-Nindigo” (2) via oxidation of a diindolopyrrole (1). The reaction of 2 with BF₃Et₂O affords the borylated derivative (3). The electronic spectra of 2 and 3 possess intense long wave absorptions near 600 and 650 nm. Compound 3 is weakly emissive in the near-infrared. Thin-film OFETs fabricated with 1 and 2 both exhibited hole mobility of 10^–5 and 10^–3 cm²/(V s), respectively.

中文翻译：

通过二吲哚并吡咯的降解意外形成半靛蓝半靛蓝

我们报告了通过diindolopyrrole（1）的氧化的靛类“半-Nindigo”（2）的偶然发现和合成。2与BF ₃ Et ₂ O的反应提供了硼化的衍生物（3）。2和3的电子光谱在600和650 nm附近具有强烈的长波吸收。化合物3在近红外中微弱发射。用1和2制成的薄膜OFET的空穴迁移率分别为10 ^–5和10 ^–3 cm ² /（V s）。

更新日期：2020-03-20

点击分享查看原文

点击收藏

阅读更多本刊最新论文