We report the synthesis and characterisation of eight constrained geometry complexes, with variation of the amido fragment, ansa-bridge, permethylindenyl group, metal centre and initiator groups from the parent complex ^Me₂SB(^tBuN,I*)TiCl₂. These complexes have been shown to be highly active for slurry-phase ethylene polymerisation when supported on solid polymethylaluminoxane (sMAO), with activities up to 7048 kg_PE/mol_Ti/h/bar. Ethylene/1-hexene and ethylene/styrene copolymerisations have shown these complexes to be good incorporators of comonomers into the polymer chain.

中文翻译：

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用于烯烃（共）聚合的第4组受约束的几何络合物

我们报告的8个几何受限络合物的合成和表征，用酰氨基片段的变体中，袢从父复杂-bridge，permethylindenyl基，金属中心和引发剂基团^我₂ SB（^吨卜N，I *）的TiCl ₂。当负载在固体聚甲基铝氧烷（sMAO）上时，这些配合物对淤浆相乙烯聚合具有很高的活性，活性高达7048 kg _PE / mol _Ti / h / bar。乙烯/ 1-己烯和乙烯/苯乙烯共聚表明这些络合物是共聚单体很好地结合到聚合物链中的。