BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions.,The Journal of Organic Chemistry

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BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions.
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2020-03-17 , DOI: 10.1021/acs.joc.9b03059
César Ray ₁ , Christopher Schad ₁ , Florencio Moreno ₁ , Beatriz L Maroto ₁ , Jorge Bañuelos ₂ , Teresa Arbeloa ₂ , Inmaculada García-Moreno ₃ , Cassie Villafuerte ₄ , Gilles Muller ₄ , Santiago de la Moya ₁

Affiliation

A general and straightforward method for the synthesis of COO-BODIPYs from F-BODIPYs and carboxylic acids is established. The method is based on the use of boron trichloride to activate the involved substitution of fluorine, which leads to high yields through rapid reactions under soft conditions. This mild method opens the way to unprecedented laser dyes with outstanding efficiencies and photostabilities, which are difficult to obtain by the current methods.

中文翻译：

BCl3活化的COO-BODIPY激光染料的合成：温和条件下的一般范围和高产率。

建立了由F-BODIPY和羧酸合成COO-BODIPY的通用直接方法。该方法基于使用三氯化硼来激活所涉及的氟取代，这通过在软条件下进行快速反应可实现高收率。这种温和的方法为前所未有的具有卓越效率和光稳定性的激光染料开辟了道路，这是当前方法难以获得的。

更新日期：2020-03-19

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