当前位置: X-MOL 学术J. Polym. Sci. A Polym. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Cover Image, Volume 57, Issue 21
Journal of Polymer Science Part A: Polymer Chemistry ( IF 2.869 ) Pub Date : 2019-11-01 , DOI: 10.1002/pola.29156


In their work reported on page 2181, Tsai and colleagues prepared a novel polyhedral oligomeric silsesquioxane (POSS)‐containing block polymer, designated as st‐PMMA‐b‐PMAPOSS, with well‐controlled stereoregularity and the ability to recognize functional molecules using a living anionic polymerization method in the presence of Lewis acid. The St‐PMMA segment in st‐PMMA‐b‐PMAPOSS formed a helical structure and encapsulated C60 in its nanocavity, resulting in the formation of about 10 nm C60 domains that lacked ordering and existed in a quasi‐equilibrium state. (DOI: 10.1002/pola.29498)
image


中文翻译:

封面图片,第57卷,第21期

在第2181页的工作报告中,Tsai及其同事制备了一种新型的含有多面体低聚倍半硅氧烷(POSS)的嵌段聚合物,命名为st- PMMA- b -PMAPOSS,具有良好的立体规则性,并且能够利用生物识别功能性分子。路易斯酸存在下的阴离子聚合方法。st- PMMA- b- PMAPOSS中的St- PMMA片段形成螺旋结构并将C 60封装在其纳米腔中,导致形成约10 nm的C 60域,这些域缺乏有序性并以准平衡态存在。(DOI:10.1002 / pola.29498)
图片
更新日期:2019-11-01
down
wechat
bug