The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle,European Journal of Organic Chemistry

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The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-03-04 , DOI: 10.1002/ejoc.202000144
Luca Capaldo ₁ , Davide Ravelli ₁

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An unprecedented perspective on photocatalytic processes is offered, with a focus on the way photocatalytic cycles are turned over. The given examples are classified according to the species responsible for photocatalyst restoration, namely: a reaction intermediate, a co‐catalyst, a reaction partner, an electrode, etc. It is demonstrated why the photocatalyst recovery is pivotal to devise an efficient synthetic protocol, showcasing how a fine tuning of this step can completely divert the reaction outcome.

中文翻译：

光催化的阴暗面：千种方法来结束循环

提供了有关光催化过程的前所未有的观点，重点是光催化循环的方式。给出的示例是根据负责光催化剂还原的物种进行分类的，即：反应中间体，助催化剂，反应伙伴，电极等。这说明了为什么光催化剂的回收对于设计有效的合成方案至关重要，展示了此步骤的微调如何完全转移反应结果。

更新日期：2020-03-04

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