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Separation of cobalt, nickel and copper with task-specific amido functionalized glycine-betaine-based ionic liquids
Separation and Purification Technology ( IF 8.6 ) Pub Date : 2020-03-05 , DOI: 10.1016/j.seppur.2020.116782
Pape Diaba Diabate , Stéphanie Boudesocque , Aminou Mohamadou , Laurent Dupont

Task Specific Ionic Liquids (TSILs) were generated by association between a cationic amido functionalized analogues of glycine-betaine (AGB) and coordinating anions such as dicyanamide (Dca-), 4-chlorosalicylate (ClSal-), saccharinate (Sac-) and weak coordinating one such as bis(trifluorosulfonyl)imide (Tf2N-). Extraction of Cu(II), Ni(II), Co(II), from pure water and salt media was performed with these AGB-ILs at room temperature. The obtained results show that in pure water Clsal based AGB-ILs have a high extraction efficiency towards these metals, whereas dicyanamide based AGB-ILs may extract efficiently Cu(II). In some cases, extraction can be improved by using simple chaotropic salts or intermediate anion such as NO3- or Cl-. Co(II) may be quantitatively extracted by Dca based AGB-ILs in NaCl 4 mol.L-1. The rational use of background salts can improve the selectivity of the extraction process and allow the separation and the recovery of the three metals separately from a mixture containing two or three divalent metals. The metal could be back-extracted from the ionic liquid phase with aqueous solution of Na2SO4, limiting the release of ionic liquid cation in aqueous media, thus preserving its integrity. The metal extractability by the Dca based ionic liquids after the stripping is quasi-equivalent to that of the fresh AGB-IL showing that it can be reused for three or four extraction and stripping cycles. A regeneration of Dca based ionic liquids after several extraction cycles is made possible by adding a solution of NaDca which restore their extractive capacity.



中文翻译:

使用任务特定的酰胺基官能化的基于甘氨酸-甜菜碱的离子液体分离钴,镍和铜

任务的具体的离子液体(功能化离子液体)通过相关联的阳离子酰氨基之间产生甘氨酸甜菜碱(AGB)的官能化的类似物和配位阴离子,如二氰胺(DCA - ),4-氯水杨酸(ClSal - ),糖精(SAC - )和弱协调一个如双(三氟磺酰)亚胺(TF 2 ñ -)。在室温下用这些AGB-IL从纯水和盐介质中萃取Cu(II),Ni(II),Co(II)。获得的结果表明,在纯水中,基于Clsal的AGB-ILs对这些金属具有很高的提取效率,而基于双氰胺的AGB-ILs可以有效地提取Cu(II)。在某些情况下,提取可以通过使用简单的离液盐或中间体阴离子如NO改善3 -或Cl - 。Co(II)可以通过Dca基AGB-IL在NaCl 4 mol.L -1中定量提取。合理使用背景盐可以提高萃取过程的选择性,并允许从包含两种或三种二价金属的混合物中分离和回收三种金属。可以使用Na 2 SO 4水溶液从离子液相中反萃取金属,从而限制离子液体阳离子在水性介质中的释放,从而保持其完整性。汽提后Dca基离子液体对金属的可萃取性与新鲜AGB-IL相当,表明它可重复使用三个或四个萃取和汽提循环。通过添加可恢复其萃取能力的NaDca溶液,可以使Dca基离子液体在几个萃取循环后再生。

更新日期:2020-03-05
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