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Surface modification of TiO2 photoanodes with In3+ using a simple soaking technique for enhancing the efficiency of dye-sensitized solar cells
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2020-03-05 , DOI: 10.1016/j.jphotochem.2020.112468
Bakhytzhan Baptayev , Salimgerey Adilov , Mannix P. Balanay

Indium-doped TiO2 photoanode for dye-sensitized solar cells are prepared using a simple surface-doping technique by soaking the TiO2 film in acidic In3+ solution at 70 °C for 30, 45 and 60 min followed by sintering at 450 °C. Structural characterization of In-doped TiO2 films by SEM, TEM, EDX, XRD and Raman spectroscopy revealed the successful attachment of Indium to the surface of TiO2 and that the amount of In dopant is proportional to the soaking time. The PCE of the devices fabricated from In-doped TiO2 with a soaking time of 30 min produced an increase of 18.0 % compared to the undoped cells. Charge extraction analysis at open-circuit revealed that surface-doping with indium shifts TiO2 band edge downward. However, the increase in VOC was found as the net effect of negative movement of CB and retarded recombination caused by TiO2 surface passivation via the In dopant.



中文翻译:

使用简单的浸泡技术用In 3+对TiO 2光阳极进行表面改性,以提高染料敏化太阳能电池的效率

使用简单的表面掺杂技术,通过将TiO 2薄膜在70°C的酸性In 3+溶液中浸泡30、45和60分钟,然后在450°烧结,使用简单的表面掺杂技术制备用于染料敏化太阳能电池的铟掺杂TiO 2光阳极。C。通过SEM,TEM,EDX,XRD和拉曼光谱对In掺杂的TiO 2薄膜进行结构表征表明,铟成功地附着在TiO 2的表面,并且In掺杂剂的量与浸泡时间成正比。由In掺杂TiO 2制成的器件的PCE与未掺杂的电池相比,浸泡时间为30分钟的电池的产量增加了18.0%。开路时的电荷提取分析表明,铟的表面掺杂使TiO 2的能带边缘向下移动。然而,发现V OC的增加是CB负向运动和因TiO 2表面通过In掺杂剂钝化而导致复合延迟的净效应。

更新日期:2020-03-05
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