Supramolecular self-assembled functional materials comprised of cyclic dipeptide building blocks have excellent prospects for biotechnology applications due to their exceptional structural rigidity, morphological flexibility, ease of preparation and modification. Although the pharmacological uses of many natural cyclic dipeptides have been studied in detail, relatively little is reported on the engineering of these supramolecular architectures for the fabrication of functional materials. In this review, we discuss the progress in the design, synthesis, and characterization of cyclic dipeptide supramolecular nanomaterials over the past few decades, highlighting applications in biotechnology and optoelectronics engineering.

由环状二肽结构单元组成的超分子自组装功能材料因其出色的结构刚性，形态柔韧性，易于制备和修饰而在生物技术领域具有广阔的前景。尽管已经详细研究了许多天然环状二肽的药理用途，但有关这些超分子结构用于功能材料制造的工程报道相对较少。在这篇综述中，我们讨论了环二肽超分子纳米材料在过去几十年中的设计，合成和表征方面的进展，重点介绍了在生物技术和光电工程中的应用。