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Broadband detection of methane and nitrous oxide using a distributed-feedback quantum cascade laser array and quartz-enhanced photoacoustic sensing.
Photoacoustics ( IF 7.1 ) Pub Date : 2019-12-26 , DOI: 10.1016/j.pacs.2019.100159
Marilena Giglio 1, 2 , Andrea Zifarelli 2 , Angelo Sampaolo 1, 2 , Giansergio Menduni 2, 3 , Arianna Elefante 2 , Romain Blanchard 4 , Christian Pfluegl 4 , Mark F Witinski 4 , Daryoosh Vakhshoori 4 , Hongpeng Wu 1 , Vittorio M N Passaro 3 , Pietro Patimisco 1, 2 , Frank K Tittel 5 , Lei Dong 1 , Vincenzo Spagnolo 1, 2
Affiliation  

Here we report on the broadband detection of nitrous oxide (N2O) and methane (CH4) mixtures in dry nitrogen by using a quartz-enhanced photoacoustic (QEPAS) sensor exploiting an array of 32 distributed-feedback quantum cascade lasers, within a spectral emission range of 1190−1340 cm−1 as the excitation source. Methane detection down to a minimum detection limit of 200 ppb at 10 s lock-in integration time was achieved. The sensor demonstrated a linear response in the range of 200−1000 ppm. Three different mixtures of N2O and CH4 in nitrogen at atmospheric pressure have been analyzed. The capability of the developed QEPAS sensor to selectively determine the N2O and CH4 concentrations was demonstrated, in spite of significant overlap in their respective absorption spectra in the investigated spectral range.



中文翻译:

使用分布式反馈量子级联激光器阵列和石英增强的光声传感技术对甲烷和一氧化二氮进行宽带检测。

在这里,我们报告使用石英增强的光声(QEPAS)传感器,利用32个分布式反馈量子级联激光器的阵列,在宽带氮气中宽带检测干燥氮气中的一氧化二氮(N 2 O)和甲烷(CH 4)混合物。光谱发射范围为1190-1340 cm -1作为激发源。在锁定时间为10 s时,甲烷检测量降至最低检测限200 ppb。传感器显示出200-1000 ppm范围内的线性响应。分析了大气压下氮气中N 2 O和CH 4的三种不同混合物。研发的QEPAS传感器选择性确定N 2 O和CH 4的能力 尽管在所研究的光谱范围内它们各自的吸收光谱有明显的重叠,但仍证明了其浓度。

更新日期:2019-12-26
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