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Structuring of the Surface Layer of Polycarbonate Film upon Interaction with Nematic Liquid Crystal
Polymer Science, Series C ( IF 1.6 ) Pub Date : 2018-10-23 , DOI: 10.1134/s181123821801006x
A. M. Parshin , V. Ya. Zyryanov , V. F. Shabanov

The structure formation observed in the surface layer of polycarbonate which proceeds when nematic liquid crystal is deposited on a film is studied. Films prepared from polycarbonate solutions in dichloromethane, chloroform, or pyridine and dried in thermobalance at different temperatures and different drying times are studied. Textures are prepared in the process of domain growth. The effect of the orientation of the disclination lines in a magnetic field and the memory effect of molecular ordering after removal and redeposition of the liquid crystal layer are observed. The process of structure formation is analyzed on the basis of the model of cooperative interaction of liquid crystal molecules with polymer chains taking into account the adsorption mechanism.



中文翻译:

与向列液晶相互作用时聚碳酸酯薄膜表面层的结构

研究了在聚碳酸酯的表层中观察到的结构形成,该结构形成是在向列液晶沉积在膜上时进行的。研究了由聚碳酸酯溶液在二氯甲烷,氯仿或吡啶中制备的薄膜,并在不同温度和不同干燥时间的热天平中对其进行干燥。在域增长过程中准备纹理。观察到旋错线的取向在磁场中的影响以及在去除和再沉积液晶层之后分子有序化的存储效果。在考虑吸附机理的基础上,基于液晶分子与聚合物链的协同相互作用模型,对结构形成过程进行了分析。

更新日期:2018-10-23
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