N‐Heterocyclic Carbene Catalyzed Photooxidation: Intramolecular Cross Dehydrogenative Coupling of Tetrahydroisoquinoline‐Tethered Aldehydes,Advanced Synthesis & Catalysis

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N‐Heterocyclic Carbene Catalyzed Photooxidation: Intramolecular Cross Dehydrogenative Coupling of Tetrahydroisoquinoline‐Tethered Aldehydes
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-03-23 , DOI: 10.1002/adsc.202000164
Zhong‐Hua Gao ₁ , Zi‐Hao Xia _{1,

2} , Lei Dai _{1,

2} , Song Ye _{1,

2}

Affiliation

An N‐heterocyclic carbene catalyzed photooxidation reaction via intramolecular cross dehydrogenative coupling of tetrahydroisoquinoline‐tethered aldehydes was developed, giving the corresponding oxidative cyclization products in moderate to good yields. This reaction features mild conditions with oxygen as the terminal oxidant in the absence of photocatalyst.

中文翻译：