Construction of a polyMOF using a polymer ligand bearing the benzenedicarboxylic acid moiety in the side chain,New Journal of Chemistry

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Construction of a polyMOF using a polymer ligand bearing the benzenedicarboxylic acid moiety in the side chain
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2020/03/03 , DOI: 10.1039/c9nj06394c
Kohei Yazaki _{1,

2,

3,

4} , Masaki Takahashi _{1,

2,

3,

4} , Naoya Miyajima _{1,

2,

3,

4} , Makoto Obata _{1,

2,

3,

4}

Affiliation

The design and synthesis of several types of metal–organic frameworks (MOFs) have been extensively reported in literature. However, the construction of MOFs using a polymer ligand (polyMOF) is still an emerging field of research. This work reports a new molecular synthetic design strategy to produce a polyMOF composed of polymer ligands with a benzenedicarboxylic acid moiety in the side chain. Powder X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy techniques were used to confirm the structures of the resulting polyMOF. Despite the film shape obtained, the resulting Zn-polyMOF showed crystalline structures, per the microscopy images obtained during powder X-ray diffraction.

中文翻译：

使用在侧链带有苯二羧酸部分的聚合物配体构建polyMOF

几种类型的金属有机框架（MOF）的设计和合成已在文献中广泛报道。但是，使用聚合物配体（polyMOF）构建MOF仍是一个新兴的研究领域。这项工作报告了一种新的分子合成设计策略，以生产由在侧链中具有苯二甲酸部分的聚合物配体组成的polyMOF。粉末X射线衍射，傅里叶变换红外光谱和扫描电子显微镜技术用于确认所得polyMOF的结构。尽管获得了膜的形状，但是根据粉末X射线衍射期间获得的显微镜图像，所得的Zn-polyMOF仍显示出晶体结构。

更新日期：2020-04-06

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