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Aerobic Oxidation of Thioglycol Catalysed by Metallophthalocyanine in an Organic-Inorganic Hybrid Vesicle “Cerasome”
Inorganic Chemistry Communications ( IF 4.4 ) Pub Date : 2020-05-01 , DOI: 10.1016/j.inoche.2020.107866
Guolin Zhang , Li Zhang , Dan Zhang , Qiuhua Wu , Yoshihiro Sasaki , Yoshio Hisaeda , Kazuma Yasuhara , Jun-ichi Kikuchi , Xi-Ming Song

Abstract A molecular assembly of a hydrophobized metallophthalocyanine derivative embedded in a cerasome, an organic–inorganic hybrid vesicle with a lipid bilayer and silica surface, was a potent catalyst for aerobic oxidation of thioglycol. The catalytic activity was higher than those in hexadecyl 2-hydroxy-3-chloropropyl phosphate vesicles, sodium dodecylsulfate micelles, ethanol, and benzene.

中文翻译:

金属酞菁在有机-无机杂化囊泡“Cerasome”中催化硫代乙二醇的好氧氧化

摘要 嵌入陶瓷体中的疏水化金属酞菁衍生物的分子组装体是一种具有脂质双层和二氧化硅表面的有机-无机杂化囊泡,是硫甘醇有氧氧化的有效催化剂。催化活性高于十六烷基2-羟基-3-氯丙基磷酸酯囊泡、十二烷基硫酸钠胶束、乙醇和苯。
更新日期:2020-05-01
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