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Novel iota carrageenan-based RhCl3 as an efficient and recyclable catalyst in Suzuki cross coupling
Molecular Catalysis ( IF 3.9 ) Pub Date : 2020-03-02 , DOI: 10.1016/j.mcat.2020.110841
Sivan Leviev , Adi Wolfson , Oshrat Levy-Ontman

RhCl3 was heterogenized into renewable polysaccharide supports, and the effect of polysaccharide type on the new catalyst performances in a Suzuki cross-coupling reaction was studied. The conversion of the fresh iota carrageenan heterogeneous system (ἰ-RhCl3), was found to be the highest, whereas it was lower than the conversion of its homogeneous analogue. In addition, the ἰ-RhCl3 (catalyst loading of 6.5 % wt) was proven to be efficient heterogeneous catalyst that was easily recycled, whereas the conversion was increased in the first and second cycles. Scanning electronic microscopy (SEM) combining Energy dispersive X-ray spectrometry and Surface analysis by X-ray photoelectron spectroscopy were performed, confirming that RhCl3 was embedded within the ἰ-carrageenan. The Fourier-transform infrared spectrometry of the heterogeneous ἰ-RhCl3 catalyst was compared to that of the native polysaccharide, and no new bands were detected. Nonetheless, a comparison of SEM image of ἰ-carrageenan with and without RhCl3, as well as rheological measurements of the aqueous solution of ἰ with and without RhCl3, indicated the incorporation of the polysaccharide with the RhCl3.



中文翻译:

新型基于iota角叉菜胶的RhCl 3作为铃木交叉偶联中的高效可回收催化剂

RhCl 3被异质化为可再生的多糖载体,并研究了多糖类型对铃木交叉偶联反应中新催化剂性能的影响。新鲜的iota卡拉胶非均相体系(ἰ-的RhCl的转化3),被认为是最高的,而这是比其均相类似物的转化率更低。另外,证明了γ-RhCl3(6.5重量%的催化剂负载量)是有效的多相催化剂,其易于再循环,而在第一和第二循环中转化率增加。进行了结合能量色散X射线光谱法和X射线光电子能谱法的表面分析的扫描电子显微镜(SEM),确认了RhCl 3被嵌入在角叉菜胶中。傅里叶变换异构ἰ-的RhCl的红外光谱3进行比较,所述天然多糖的催化剂,并没有检测到新的谱带。尽管如此,ἰ角叉菜胶具有和不具有的RhCl的SEM图像的比较3,以及具有和不具有的RhClἰ的水溶液的流变学测量3,所示的多糖的结合与所述的RhCl 3

更新日期:2020-03-02
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