Materials Today Communications ( IF 3.7 ) Pub Date : 2020-03-02 , DOI: 10.1016/j.mtcomm.2020.101042 Zhenyun Zhao , Jing Zhou , Hang Xiao , Yiping Liu , Ming Lu
Incorporation of PANI with polyethylene terephthalate (PET) fibers has creates many flexible conductive, electrothermal and energy-storage textiles. The most common method of depositing PANI to PET fibers is in-situ polymerization. However, it usually needs long reaction time and strict conditions, which is unbeneficial to large-scale commercialized process. Herein, a facile and high-efficiency surface micro-dissolution method was proposed to prepare PANI-coated PET fabrics, which is performed at moderate temperature (70 °C) and only needs 15 min of treatment time. Already-made PANI powders were directly used as raw materials, and the phenol/N-methyl pyrrolidone (phenol/NMP) solution worked as the surface micro-dissolution agent. The resulting fabrics show electroconductive (620 Ω/□), electrothermal (from 22.3–30.3 ℃ within 1 min) and energy storage (438.51 m F cm−2) performances. The preparation is easy to perform and of very high efficiency, making it suitable for industrial production of PANI-coated PET fabrics.
中文翻译:
通过微溶解法创建具有导电,电热和储能性能的聚苯胺涂层聚酯织物
PANI与聚对苯二甲酸乙二酯(PET)纤维的结合产生了许多柔软的导电,电热和储能纺织品。将PANI沉积到PET纤维上最常见的方法是原位聚合。但是,它通常需要较长的反应时间和严格的条件,这不利于大规模的商业化工艺。在此,提出了一种简便高效的表面微溶解方法来制备PANI涂层的PET织物,该方法在中等温度(70°C)下进行,仅需要15分钟的处理时间。已有的PANI粉末直接用作原料,苯酚/ N-甲基吡咯烷酮(苯酚/ NMP)溶液用作表面微溶解剂。所得织物显示出导电性(620Ω/□),电热性(1分钟内从22.3–30.3℃起)和能量存储(438.51 m F cm -2)性能。该制备易于进行且效率非常高,使其适合工业生产PANI涂层的PET织物。