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Simple isophthalamides/dipicolineamides as active transmembrane anion transporters
Supramolecular Chemistry ( IF 2.1 ) Pub Date : 2019-12-14 , DOI: 10.1080/10610278.2019.1702194 Giacomo Picci 1 , Israel Carreira-Barral 2 , Daniel Alonso-Carrillo 2 , David Sanz-González 2 , Pablo Fernández-López 2 , María García-Valverde 2 , Claudia Caltagirone 1 , Roberto Quesada 2
Supramolecular Chemistry ( IF 2.1 ) Pub Date : 2019-12-14 , DOI: 10.1080/10610278.2019.1702194 Giacomo Picci 1 , Israel Carreira-Barral 2 , Daniel Alonso-Carrillo 2 , David Sanz-González 2 , Pablo Fernández-López 2 , María García-Valverde 2 , Claudia Caltagirone 1 , Roberto Quesada 2
Affiliation
ABSTRACT Eight N,N´-diarylisophthalamide/dipicolineamide derivatives have been synthesised and fully characterised, both in solution and in the solid state. The transmembrane anion transport properties of these compounds have been studied by chloride-selective electrode and fluorescence experiments. The substitution pattern of the aromatic moieties determines the transport properties of these systems, with those containing electron-withdrawing groups in their structures being the most active ones of the series. Graphical abstract
中文翻译:
作为活性跨膜阴离子转运蛋白的简单间苯二甲酰胺/二吡啶甲酰胺
摘要 八种 N,N'-二芳基间苯二甲酰胺/二吡啶甲酰胺衍生物已被合成并充分表征,无论是在溶液中还是在固态中。通过氯离子选择性电极和荧光实验研究了这些化合物的跨膜阴离子传输特性。芳族部分的取代模式决定了这些系统的传输特性,其中结构中含有吸电子基团的那些是该系列中最活跃的。图形概要
更新日期:2019-12-14
中文翻译:
作为活性跨膜阴离子转运蛋白的简单间苯二甲酰胺/二吡啶甲酰胺
摘要 八种 N,N'-二芳基间苯二甲酰胺/二吡啶甲酰胺衍生物已被合成并充分表征,无论是在溶液中还是在固态中。通过氯离子选择性电极和荧光实验研究了这些化合物的跨膜阴离子传输特性。芳族部分的取代模式决定了这些系统的传输特性,其中结构中含有吸电子基团的那些是该系列中最活跃的。图形概要