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Enhanced red-emission of β-NaYF4: Er3+/Eu3+ microparticles via energy transfer with La3+ doping
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 2020-02-29 , DOI: 10.1016/j.jfluchem.2020.109503
Qianhong Bo , Jinliang Wang

In this paper hexagonal trivalent lanthanide ions (Ln3+) doped β-NaYF4 microparticles were synthesized by a facile hydrothermal method. The structure, morphology and composition of the microparticles were confirmed by XRD, SEM, EDS. Multicolor luminescence was observed. The up-conversion(UC) and down conversion emission intensity of β-NaYF4: Ln3+ (Ln3+=Er3+, Eu3+) microparticles and the red-emission of β-NaYF4:Er3+/Eu3+ microparticles were increased. The La3+ ions doped the samples enhancing energy transfer between the Ln3+ ions by altering the crystal field symmetry around Ln3+ is described.



中文翻译:

的增强的红色发光β-NaYF 4:铒3+ / EU 3+经由与拉能量转移微粒3+掺杂

本文六边形的三价镧系元素离子(LN 3+)掺杂β-NaYF 4个微粒通过一个浅显的水热法合成。通过XRD,SEM,EDS证实了微粒的结构,形态和组成。观察到多色发光。上转换(UC)和向下转换发射强度β-NaYF 4:LN 3+(LN 3+ =尔3+,Eu的3+)微粒和红色发光β-NaYF 4:铒3+ / Eu 3+微粒增加。La 3+离子掺杂了样品,从而增强了Ln 3+之间的能量转移描述了通过改变Ln 3+周围的晶体场对称性产生的离子

更新日期:2020-03-02
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