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Reduction of SO2 to elemental sulfur with carbon materials through electrical and microwave heating methods
Chemical Engineering and Processing: Process Intensification ( IF 3.8 ) Pub Date : 2020-02-28 , DOI: 10.1016/j.cep.2020.107877
Xiao Xia , Xiqiang Zhao , Ping Zhou , Tai Feng , Chunyuan Ma , Zhanlong Song

To develop a new process for reducing SO2 to elemental sulfur, the reduction of SO2 with carbon materials heated by electrical and microwave were investigated on a fixed bed experimental system. The effects of carbon species, temperature, SO2 concentration and C/SO2 molar ratio on SO2 reduction were studied. The results showed that coconut shell activated carbon has the best reduction effect among the six carbon materials. With the increase of reaction temperature, the XSO2 gradually increased. However, the YS rapidly decreased at 800°C and reached a minimum value of only 55 % at 900℃. The XSO2 increased with the increase of C/S mole ratio, but the YS showed a different trend according to the different reaction temperature. By comparing the effects of microwave heating and electrical heating on the reduction of SO2, the much lower temperature was required to obtain the same XSO2 under microwave heating than that under electrical heating. Also for the SS, the results obtained under microwave heating were higher than that of electrical heating. When the reaction temperature was 950℃, XSO2 was about 98 % under both heating modes. However, YS under microwave heating was 95 %, while YS under electrical heating was only 85 %.



中文翻译:

通过电和微波加热方法用碳材料将SO 2还原为元素硫

为了开发一种将SO 2还原为元素硫的新方法,在固定床实验系统上研究了用电和微波加热的碳材料还原SO 2的方法。研究了碳的种类,温度,SO 2浓度和C / SO 2摩尔比对SO 2还原的影响。结果表明,椰壳活性炭在六种碳材料中还原效果最好。随着反应温度的升高,X SO2逐渐增加。然而,Y S在800℃迅速下降,在900℃达到最小值的55%。该X SO2随C / S摩尔比的增加而增加,但Y S随反应温度的不同呈现出不同的趋势。通过比较微波加热和电加热对SO 2还原的影响,与电加热相比,在微波加热下获得相同的X SO2所需的温度要低得多。同样对于S S,在微波加热下获得的结果高于电加热的结果。当反应温度为950℃时,两种加热模式下的X SO2均约为98%。但是,微波加热下的Y S为95%,而Y S 在电加热下仅为85%。

更新日期:2020-02-28
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