One-pot conversion of mechanically activated cellulose to sorbitol was investigated over bifunctional catalysts based on Ru (0.6, 1 and 3 wt.%) and cesium salts of heteropoly acids (HPA) Cs_2.1H_0.9PW₁₂O₄₀ and Cs₃HSiW₁₂O₄₀ (Cs-PW and Cs-SiW, respectively). The maximal yield of sorbitol equal to 59% and selectivity 94% were achieved over the 1%Ru/Cs₃HSiW₁₂O₄₀ catalyst. Physicochemical and catalytic data showed that the rate-determining step, i.e. the hydrolysis of cellulose, depended on the surface acidity of catalysts, whereas Ru content in catalyst affected both the hydrolysis and the hydrogenation steps. The kinetic parameters for one-pot conversion of cellulose were determined by mathematical modeling approach and were successfully used for the prediction of the yields of sorbitol and mannitol.

在基于Ru（0.6、1和3 wt。％）和杂多酸（HPA）铯盐Cs _2.1 H _0.9 PW ₁₂ O ₄₀和Cs ₃ HSiW _12的双功能催化剂上研究了机械活化纤维素向山梨糖醇的一锅转化。O ₄₀（分别为Cs-PW和Cs-SiW）。在1％Ru / Cs ₃ HSiW ₁₂ O _40上，山梨糖醇的最大产率等于59％，选择性达到94％催化剂。物理化学和催化数据表明，决定速率的步骤（即纤维素的水解）取决于催化剂的表面酸度，而催化剂中的Ru含量影响水解和氢化步骤。通过数学建模方法确定了纤维素一锅转化的动力学参数，并成功地用于预测山梨醇和甘露醇的收率。