The ab initio quasirelativistic approach developed specifically for the calculation of spectral parameters of highly charged ions was used to derive transition data for the Nb-like tungsten ion W³³⁺. The configuration interaction method was applied to include electron correlation effects. The relativistic effects were taken into account in the Breit–Pauli approximation. The level energies, radiative lifetimes $\tau$, Landé $g$-factors were determined for the ground configuration 4p⁶4d⁵ and two excited configurations 4p⁵4d⁶ and 4p⁶4d⁴4f. The radiative transition wavelengths $\lambda$ and emission transition probabilities $A$ for the electric dipole, electric quadrupole, electric octupole, magnetic dipole, and magnetic quadrupole transitions among the levels of these configurations were produced. The uncertainties of computed spectroscopic parameters were evaluated.

在从头专门为高度带电的离子的光谱参数的计算开发quasirelativistic方法被用来推导过渡数据为将Nb状钨离子W¯¯ ³³⁺。应用构型相互作用方法包括电子相关效应。在布赖特-保利近似中考虑了相对论的影响。能级能量，辐射寿命$\tau$，朗德 $G$确定接地构型4p ⁶ 4d ⁵和两个励磁构型4p ⁵ 4d ⁶和4p ⁶ 4d ⁴ 4f的α-因子。辐射跃迁波长$\lambda$ 和排放过渡概率 $\mathrm{一种}$对于电偶极子，在这些配置的级别之间产生了电四极子，八极子，磁偶极子和磁四极子跃迁。评估了计算光谱参数的不确定性。