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Progress in the growth of CaCu3Ti4O12 and related functional dielectric perovskites
Progress in Crystal Growth and Characterization of Materials ( IF 5.1 ) Pub Date : 2014-06-01 , DOI: 10.1016/j.pcrysgrow.2014.04.001
Laxman Singh , U.S. Rai , K.D. Mandal , N.B. Singh

Abstract Calcium copper titanate, CaCu3Ti4O12, (CCTO), a potential electro-ceramic is a member of a very important perovskite family and has been found to a show dielectric constant of the order of 104–105. It has a remarkable ability to undergo a series of cationic exchange reactions resulting in corresponding isomorphs. In the past decade there has been immense activity in the search of an isomorph of CCTO with high dielectric constant and low loss which enables its use as capacitor material for the storage of energy and miniaturization of electronic based equipment. Despite intensive research in the area there is no source of any literature that gives all the possible relevant information regarding various synthetic methods, characterizations, effect of sintering parameters (temperature, duration, and atmosphere). This review article is an effort to review the synthesis, grain growth, morphological evolution, effect of impurities, substitution and interface anisotropy on the dielectric constant, resistivity and other materials parameters.

中文翻译:

CaCu3Ti4O12及相关功能性介电钙钛矿的生长进展

摘要 钛酸铜钙CaCu3Ti4O12 (CCTO) 是一种潜在的电陶瓷,是非常重要的钙钛矿家族的一员,已发现其介电常数约为104-105。它具有显着的能力,可以进行一系列的阳离子交换反应,产生相应的同晶型物。在过去的十年中,在寻找具有高介电常数和低损耗的 CCTO 同晶型方面开展了大量活动,使其能够用作电容器材料,用于能量存储和电子设备的小型化。尽管在该领域进行了深入研究,但没有任何文献来源提供有关各种合成方法、特征、烧结参数影响(温度、持续时间和气氛)的所有可能的相关信息。
更新日期:2014-06-01
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