ABSTRACT The solubility of ozone in the aqueous solutions of acids, HClO4 and H2SO4, and salts, LiClO4, NaClO4, KClO4, Mg(ClO4)2, Ca(ClO4)2, NaCl, KCl, Na2SO4, K2SO4, and NaNO3, is studied. On the basis of experimental results and published data, the values of the Weisenberger-Schumpe model parameters for the perchlorate ion and ozone are proposed to be = 0.0391 M−1 and hG,0 = −0.0152 M−1 (t = 25°C), respectively. The values of the similar parameters for the van Krevelen-Hoftijzer model are found to be = 0.336 M−1 and xG = −0.215 M−1, respectively. The discrepancies between the values of Sechenov constants calculated using the van Krevelen-Hoftijzer model for the one-component salty solutions, are somewhat smaller than between those determined using the Weisenberger-Schumpe model. The Sechenov constants are satisfactorily predicted (to a ~ 20% accuracy) by the Weisenberger-Schumpe model with the new and hG,0 values.

中文翻译：

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臭氧在高氯酸盐和其他电解质水溶液中的溶解度：修正用于 ClO4− 和 O3 的 Weisenberger-Schumpe 模型参数

摘要 研究了臭氧在酸、HClO4 和 H2SO4 以及盐类 LiClO4、NaClO4、KClO4、Mg(ClO4)2、Ca(ClO4)2、NaCl、KCl、Na2SO4、K2SO4 和 NaNO3 的水溶液中的溶解度. 根据实验结果和公布的数据，高氯酸根离子和臭氧的 Weisenberger-Schumpe 模型参数值建议为 = 0.0391 M-1 和 hG,0 = -0.0152 M-1 (t = 25°C ）， 分别。发现 van Krevelen-Hoftijzer 模型的相似参数值分别为 = 0.336 M-1 和 xG = -0.215 M-1。对于单组分盐溶液，使用 van Krevelen-Hoftijzer 模型计算的 Sechenov 常数值之间的差异略小于使用 Weisenberger-Schumpe 模型确定的值之间的差异。