Journal of Macromolecular Science Part B-Physics ( IF 1.2 ) Pub Date : 2019-03-07 , DOI: 10.1080/00222348.2019.1574424 Martina Kaszonyiova 1 , Frantisek Rybnikar 1
The phase II to I transformation process of isotactic polybutene – 1 (iPB-1) is influenced by the environment besides the usual physical factors. The phase II → I transformation rate depends, first of all, on the segmental mobility of the polymer chains. Environmental substances which are good solvents of iPB-1 increased the phase transformation rate at room temperature. Other substances, such as air, water, some acids or blends with atactic polypropylene, decreased the transformation rate in comparison with a sample exposed to a phosphorus pentoxide desiccant environment. The environmental effects also influence several other structural characteristics, such as sample crystallinity and crystallite size.
中文翻译:
环境对等规聚丁烯-1的II-I期转化的影响。
等规聚丁烯-1(iPB-1)从II到I的相变过程除了通常的物理因素外,还受环境的影响。II→I相的转化率首先取决于聚合物链的节段迁移率。作为iPB-1良好溶剂的环境物质在室温下提高了相变速率。与暴露于五氧化二磷干燥剂环境的样品相比,其他物质(例如空气,水,某些酸或与无规聚丙烯的混合物)降低了转化率。环境影响还影响其他几个结构特征,例如样品的结晶度和微晶尺寸。