Conversion of furfural to tetrahydrofuran-derived secondary amines under mild conditions,Green Chemistry

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Conversion of furfural to tetrahydrofuran-derived secondary amines under mild conditions
Green Chemistry ( IF 9.3 ) Pub Date : 2020/02/28 , DOI: 10.1039/d0gc00119h
Shi Jiang _{1,

2,

3,

4,

5} , Eric Muller _{3,

6,

7} , François Jerôme _{1,

2,

3} , Marc Pera-Titus _{4,

5,

8,

9} , Karine De Oliveira Vigier _{1,

2,

3}

Affiliation

The production of amino-containing compounds from biomass is an important goal of research programs. Starting from carbohydrate-based furfural, a simple and highly efficient system was developed for producing a library of secondary and tertiary tetrahydrofurfurylamines under mild conditions (25 °C/1 bar H₂) with excellent yields (>90%). Commercially available Pd/Al₂O₃ proved to be a suitable catalyst and exhibited outstanding performance.

中文翻译：

在温和条件下将糠醛转化为四氢呋喃衍生的仲胺

由生物质生产含氨基化合物是研究计划的重要目标。从基于碳水化合物的糠醛开始，开发了一种简单高效的系统，可在温和条件下（25°C / 1 bar H ₂）以优异的收率（> 90％）生产仲和叔四氢糠胺库。市场上可买到的Pd / Al ₂ O ₃被证明是合适的催化剂，并表现出出色的性能。

更新日期：2020-03-24

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