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Conversion of furfural to tetrahydrofuran-derived secondary amines under mild conditions
Green Chemistry ( IF 9.3 ) Pub Date : 2020/02/28 , DOI: 10.1039/d0gc00119h
Shi Jiang 1, 2, 3, 4, 5 , Eric Muller 3, 6, 7 , François Jerôme 1, 2, 3 , Marc Pera-Titus 4, 5, 8, 9 , Karine De Oliveira Vigier 1, 2, 3
Affiliation  

The production of amino-containing compounds from biomass is an important goal of research programs. Starting from carbohydrate-based furfural, a simple and highly efficient system was developed for producing a library of secondary and tertiary tetrahydrofurfurylamines under mild conditions (25 °C/1 bar H2) with excellent yields (>90%). Commercially available Pd/Al2O3 proved to be a suitable catalyst and exhibited outstanding performance.

中文翻译:

在温和条件下将糠醛转化为四氢呋喃衍生的仲胺

由生物质生产含氨基化合物是研究计划的重要目标。从基于碳水化合物的糠醛开始,开发了一种简单高效的系统,可在温和条件下(25°C / 1 bar H 2)以优异的收率(> 90%)生产仲和叔四氢糠胺库。市场上可买到的Pd / Al 2 O 3被证明是合适的催化剂,并表现出出色的性能。
更新日期:2020-03-24
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