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Absolute configurations of talaromycones A and B, α-diversonolic ester, and aspergillusone B from endophytic Talaromyces sp. ECN211
Beilstein Journal of Organic Chemistry ( IF 2.2 ) Pub Date : 2020-02-28 , DOI: 10.3762/bjoc.16.28 Ken-ichi Nakashima , Junko Tomida , Takao Hirai , Yoshiaki Kawamura , Makoto Inoue
Beilstein Journal of Organic Chemistry ( IF 2.2 ) Pub Date : 2020-02-28 , DOI: 10.3762/bjoc.16.28 Ken-ichi Nakashima , Junko Tomida , Takao Hirai , Yoshiaki Kawamura , Makoto Inoue
Talaromycones A (1) and B (2), new xanthenediones, were isolated from the cultures of Talaromyces sp. ECN211, an endophytic fungus, along with α-diversonolic ester (3), aspergillusone B (4), glauconic acid (5), and rosellisin (6). The planar structures of 1 and 2 were elucidated by extensive spectroscopic analyses. Furthermore, the absolute configurations of 1–4 were determined by single-crystal X-ray diffraction and electronic circular dichroism spectroscopy (ECD). In addition, the crystallographic data for 5 were updated for the first time in over 50 years.
中文翻译:
内生Talaromyces sp。的talalomycones A和B,α-二磺酸酯和曲霉酮B的绝对构型。ECN211
Talaromycones A(1)和B(2),新的xanthenediones,是从Talaromyces sp。的培养物中分离出来的。ECN211,一种内生真菌,以及α-双磺酸酯(3),曲霉酮B(4),葡糖二酸(5)和玫瑰果素(6)。通过广泛的光谱分析阐明了1和2的平面结构。此外,的绝对构型1 - 4通过单晶X射线衍射和电子圆二色光谱(ECD)来确定。另外,晶体学数据为5 是50多年来第一次更新。
更新日期:2020-02-28
中文翻译:
内生Talaromyces sp。的talalomycones A和B,α-二磺酸酯和曲霉酮B的绝对构型。ECN211
Talaromycones A(1)和B(2),新的xanthenediones,是从Talaromyces sp。的培养物中分离出来的。ECN211,一种内生真菌,以及α-双磺酸酯(3),曲霉酮B(4),葡糖二酸(5)和玫瑰果素(6)。通过广泛的光谱分析阐明了1和2的平面结构。此外,的绝对构型1 - 4通过单晶X射线衍射和电子圆二色光谱(ECD)来确定。另外,晶体学数据为5 是50多年来第一次更新。