This article summarizes several approaches for understanding the catalytic chemistry and “structure-surface acidity-reactivity” relationships in a multiplicity of catalytic applications of a continually increasing assemblage of metal-organic frameworks (MOFs) structures. The various spectroscopic techniques for acid-base characterization of MOFs are reviewed. The experimental requirements and the type and nature of probe molecules available are also discussed. Special emphasis is given to the revealing of the surface acid-base effect on the catalytic performance of MOFs.

中文翻译：

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金属有机骨架的酸碱性质和催化活性：光谱和半经验方法的观点

本文总结了几种理解金属-有机骨架（MOFs）结构不断增加的组合在多种催化应用中的催化化学和“结构-表面酸性-反应性”关系的方法。综述了用于MOF酸碱表征的各种光谱技术。还讨论了实验要求以及可用的探针分子的类型和性质。特别强调了表面酸碱效应对MOFs催化性能的揭示。