In this article we discussed synthesis and catalytic applications of heterogeneous catalysts based on lacunary polyoxometalates (LPOMs) and transition metal substituted polyoxometalates (TMSPOMs), however exclusively the focus has been given to the mono LPOMs and mono-TMSPOMs. As the field of supported LPOMs/TMSPOMs is upcoming important field, some aspects about choice of support as well as methods of supporting have also been described. We also include a few of our new research results in order to understand the effect of support and active species as well as choice of organic transformation.

中文翻译：

---

Keggin型金相和过渡金属取代的多金属氧酸盐作为多相催化剂的研究进展

在本文中，我们讨论了基于金属多金属氧酸盐（LPOM）和过渡金属取代的多金属氧酸盐（TMSPOM）的非均相催化剂的合成和催化应用，然而，重点一直放在单LPOM和单TMSPOM上。由于受支持的LPOM / TMSPOM领域即将成为重要领域，因此还描述了有关支持选择以及支持方法的某些方面。我们还包括一些新的研究成果，以了解支持物和活性物种的作用以及有机转化的选择。