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Environmentally friendly CsPbBr3 QDs multicomponent glass with super-stability for optoelectronic devices and up-converted lasing
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2020-02-27 , DOI: 10.1016/j.jeurceramsoc.2020.02.056
Shasha Li , Lanjian Nie , Shumin Ma , Guanpeng Yao , Fanming Zeng , XinYu Wang , Chunyi Sun , Guangxu Hu , Zhongmin Su

Ultra-stable CsPbBr3 perovskite quantum dots (QDs) multicomponent glass with high transmittance was prepared by melt-quenching heat treatment. The average diameter of the CsPbBr3 QDs was ∼1.96 nm. The resulting glass displayed a high exciton binding energy of 362 ± 18 meV. Notably, these glass-encapsulated materials exhibited excellent resistance to heat, light, and water, superior to that of previously reported perovskite-based materials, and underwent an extremely low rate of Pb leaching during water immersion. Based on the glass, a high-performance white light-emitting diode (WLED) device was fabricated with Commission Internationale de L’Eclairage (CIE) coordinates of (0.3156, 0.3326) and color gamut of ∼113 % National Television Standards Committee (NTSC). The CsPbBr3 QDs glass without rare earth elements further acted as an optical gain medium, realizing up-conversion lasing with 980-nm laser excitation for the first time. The reversible linear fluorescence response indicates that the glass could be a potential candidate for temperature sensors.



中文翻译:

具有超稳定性的环保型CsPbBr 3 QDs多组分玻璃,用于光电器件和上转换激光

通过熔融淬火热处理制备了具有高透射率的超稳定CsPbBr 3钙钛矿量子点(QDs)多组分玻璃。CsPbBr 3 QD的平均直径约为1.96 nm。所得玻璃显示出362±18meV的高激子结合能。值得注意的是,这些玻璃封装材料表现出优异的耐热,耐光和防水性能,优于先前报道的钙钛矿基材料,并且在浸入水中时铅的浸出率极低。以玻璃为基础,制造了一种高性能的白光发光二极管(WLED)器件,其国际照明委员会(CIE)坐标为(0.3156,0.3326),色域为〜113%国家电视标准委员会(NTSC) )。溴化铯不含稀土元素的3 QDs玻璃进一步充当光增益介质,首次通过980 nm激光激发实现上转换激光。可逆的线性荧光响应表明玻璃可能是温度传感器的潜在候选者。

更新日期:2020-02-27
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