Abstract—

The potential profiles at the boundary with the ion-exchange membrane and near the current feeder and the current and concentration profiles of the target electroactive component along the solution flow in the galvanostatic mode are calculated at various current loads using a simplified model of porous electrode. From the analysis of the calculated results, it follows that the potential profiles vary significantly depending on the current and the presence or absence of a side reaction. The results can be used for preliminary estimation of electrolysis mode, which provides the highest efficiency of porous electrode operation.

中文翻译：

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在不同电流下流通的多孔电极内膜的边界处的电位分布分析。第一部分建模

摘要-

使用多孔电极的简化模型，在各种电流负载下，计算了在恒电流模式下沿离子流与离子交换膜交界处和靠近进料器的边界处的电势分布以及目标电活性组分沿溶液流的电流和浓度分布。从对计算结果的分析可以看出，电位分布根据电流的大小以及是否存在副反应而有很大不同。结果可用于初步估算电解模式，从而提供最高的多孔电极操作效率。