Rates of Ring Opening of Radical Cation Intermediates Govern Differences in Thermoluminescence between 1‐ and 2‐Naphthyl‐Substituted Methylenecyclopropanes,ChemPhotoChem

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Rates of Ring Opening of Radical Cation Intermediates Govern Differences in Thermoluminescence between 1‐ and 2‐Naphthyl‐Substituted Methylenecyclopropanes
ChemPhotoChem ( IF 3.0 ) Pub Date : 2020-02-27 , DOI: 10.1002/cptc.202000019
Yasunori Matsui _{1,

2} , Kazuki Shimono ₁ , Kosuke Takae ₁ , Hayato Namai ₃ , Toshiki Sera ₁ , Takuya Ogaki ₁ , Eisuke Ohta _{1,

2} , Kazuhiko Mizuno _{1,

2} , Hiroshi Ikeda _{1,

2}

Affiliation

The front cover artwork is provided by the group of Prof. Dr. Hiroshi Ikeda in Osaka Prefecture University (Japan). The picture represents the difference in reactivity between 1‐ and 2‐naphthyl‐substituted methylenecyclopropanes. The weak bond in the former substance can be broken even by a small samurai resulting in pink fluorescence, whereas the strong bond in the latter cannot be broken even by a big samurai (resulting in green phosphorescence). Read the full text of the Communication at 10.1002/cptc.201900230.

中文翻译：

自由基阳离子中间体的开环速率控制1和2萘基取代的亚甲基环丙烷之间的热致发光差异

封面艺术品由日本大阪府大学的池田宏志教授提供。图片显示了1和2萘基取代的亚甲基环丙烷之间的反应性差异。即使是小的武士也会破坏前者物质中的弱键，导致发出粉红色荧光，而即使是大武士也不会破坏后者中的强键（导致绿色磷光）。阅读通讯的全文10.1002 / cptc.201900230。

更新日期：2020-02-27

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