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Recent progress in C(aryl)–C(alkyl) bond cleavage of alkylarenes
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020/02/26 , DOI: 10.1039/c9qo01438a Peng-Fei Dai 1, 2, 3, 4, 5 , Hua Wang 5, 6, 7, 8 , Xian-Chao Cui 5, 6, 7, 8 , Jian-Ping Qu 1, 2, 3, 4, 5 , Yan-Biao Kang 5, 6, 7, 8
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020/02/26 , DOI: 10.1039/c9qo01438a Peng-Fei Dai 1, 2, 3, 4, 5 , Hua Wang 5, 6, 7, 8 , Xian-Chao Cui 5, 6, 7, 8 , Jian-Ping Qu 1, 2, 3, 4, 5 , Yan-Biao Kang 5, 6, 7, 8
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Cleavage of the C(aryl)–C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However, C(aryl)–C(alkyl) bonds of alkylarenes remain intact under most conventional reaction conditions. In this review, we highlight the results of recent C(aryl)–C(alkyl) bond cleavages that have been induced by homogeneous transition metal reagents, by oxidative cleavages, and by rearrangement.
中文翻译：
烷基芳烃的C（芳基）–C（烷基）键裂解的最新进展
裂解C（芳基）–C（烷基）的σ键在学术界和工业界都很重要，因为它具有从直接可得的化学原料（如烷基芳烃）提供直接接触各种目标的潜力。但是，在大多数常规反应条件下，烷基芳烃的C（芳基）–C（烷基）键保持完整。在这篇综述中，我们重点介绍了均相过渡金属试剂，氧化裂解和重排引起的最近C（芳基）–C（烷基）键裂解的结果。
更新日期：2020-03-19
中文翻译：
烷基芳烃的C（芳基）–C（烷基）键裂解的最新进展
裂解C（芳基）–C（烷基）的σ键在学术界和工业界都很重要，因为它具有从直接可得的化学原料（如烷基芳烃）提供直接接触各种目标的潜力。但是，在大多数常规反应条件下，烷基芳烃的C（芳基）–C（烷基）键保持完整。在这篇综述中，我们重点介绍了均相过渡金属试剂，氧化裂解和重排引起的最近C（芳基）–C（烷基）键裂解的结果。
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