Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution,Chemical Communications

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Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution
Chemical Communications ( IF 4.3 ) Pub Date : 2020/02/26 , DOI: 10.1039/d0cc00879f
Xiaomin Chai _{1,

2,

3,

4} , Hai-Hua Huang _{4,

5,

6,

7,

8} , Huiping Liu _{1,

2,

3,

4} , Zhuofeng Ke _{4,

5,

6,

7,

8} , Wen-Wen Yong _{4,

9,

10,

11,

12} , Ming-Tian Zhang _{4,

9,

10,

11,

12} , Yuan-Sheng Cheng _{1,

2,

3,

4} , Xian-Wen Wei _{1,

2,

3,

4} , Liyan Zhang _{1,

2,

3,

4} , Guozan Yuan _{1,

2,

3,

4}

Affiliation

Five molecular complexes with different non-noble metal centers were synthesized. The Co-based complex displays the highest photocatalytic performance for CO₂ to CO conversion in aqueous media. It achieves high activity (TON = 41 017 and TOF = 3.80 s⁻¹) and selectivity (87%) for the production of CO.

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