The power of dissociation: development of displacement assays for chemosensing and latent catalytic systems,Materials Chemistry Frontiers

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The power of dissociation: development of displacement assays for chemosensing and latent catalytic systems
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2020-02-26 , DOI: 10.1039/c9qm00639g
Cheuk-Fai Chow _{1,

2,

3} , Anxun Zheng _{1,

2,

3} , Min Huang _{1,

2,

3} , Chang Shen _{1,

2,

3}

Affiliation

Disassembly is an essential process in supramolecular chemistry, and its exploitation has resulted in the development of four different displacement assays: (a) indicator-displacement assay (IDA), (b) indicator/catalyst-displacement assay (ICDA), (c) catalytic/indicator-displacement assay (CIDA), and (d) catalyst-displacement assay (CDA). These consist of bimetallic donor–acceptor ensembles (BmDAEs), which incorporate various metallic signal transducers, receptors, inhibitors, catalysts, and pre-catalysts. Applications thereof include pollutant degradation, signal amplification, chemosensing detection, and latent catalysis. This review discusses the use of bimetallic supramolecular systems for the development of catalysts, chemosensors, and chemodosimeters.

中文翻译：

解离的力量：化学传感和潜在催化系统的位移测定法的发展

拆卸是超分子化学中必不可少的过程，其开发已导致开发了四种不同的置换测定：（a）指示剂置换测定（IDA），（b）指示剂/催化剂置换测定（ICDA），（c）催化/指标置换试验（CIDA）和（d）催化剂置换试验（CDA）。这些由双金属供体-受体组（BmDAE）组成，其中包含各种金属信号转导剂，受体，抑制剂，催化剂和预催化剂。其应用包括污染物降解，信号放大，化学传感检测和潜在催化。这篇综述讨论了使用双金属超分子系统开发催化剂，化学传感器和化学计量仪。

更新日期：2020-02-26

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