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A multiple hydrogen-bonded three-dimensional supramolecular architecture composed of a unique three-fold interlocked anionic Zn(II)-coordination architecture
CrystEngComm ( IF 2.6 ) Pub Date : 2020/02/26 , DOI: 10.1039/d0ce00177e
Hua Ke 1, 2, 3, 4, 5 , Qi-Hua Chen 1, 2, 3, 4 , Jian-Zhen Liao 1, 2, 3, 4, 5 , Can-Zhong Lu 4, 5, 6, 7, 8
Affiliation  

An unprecedented three-dimensional multiple hydrogen bonded supramolecular framework containing an interlocked three-fold self-knitting structural topology, which is based on a pseudo graphene-like unweaving monolayer of a Zn(II)-coordination complex, is obtained via a solvothermal synthesis method. Two different large cavities are generated in this supramolecular architecture. Furthermore, the investigation of the Hirshfeld surface analysis reproduces the results of an X-ray crystal structure analysis and expounds the intermolecular interactions experienced by complexes in a visual manner.

中文翻译:

多重氢键键合的三维超分子结构,由独特的三重互锁阴离子Zn(II)配位结构组成

通过溶剂热合成法获得了前所未有的三维多重氢键超分子骨架,该骨架包含互锁的三重自编织结构拓扑,该结构拓扑基于Zn(II)配位络合物的假石墨烯状无纺单层。。在这种超分子结构中产生了两个不同的大空腔。此外,对Hirshfeld表面分析的研究重现了X射线晶体结构分析的结果,并以可视的方式阐述了配合物经历的分子间相互作用。
更新日期:2020-03-30
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