A multiple hydrogen-bonded three-dimensional supramolecular architecture composed of a unique three-fold interlocked anionic Zn(II)-coordination architecture,CrystEngComm

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A multiple hydrogen-bonded three-dimensional supramolecular architecture composed of a unique three-fold interlocked anionic Zn(II)-coordination architecture
CrystEngComm ( IF 2.6 ) Pub Date : 2020/02/26 , DOI: 10.1039/d0ce00177e
Hua Ke _{1,

2,

3,

4,

5} , Qi-Hua Chen _{1,

2,

3,

4} , Jian-Zhen Liao _{1,

2,

3,

4,

5} , Can-Zhong Lu _{4,

5,

6,

7,

8}

Affiliation

An unprecedented three-dimensional multiple hydrogen bonded supramolecular framework containing an interlocked three-fold self-knitting structural topology, which is based on a pseudo graphene-like unweaving monolayer of a Zn(II)-coordination complex, is obtained via a solvothermal synthesis method. Two different large cavities are generated in this supramolecular architecture. Furthermore, the investigation of the Hirshfeld surface analysis reproduces the results of an X-ray crystal structure analysis and expounds the intermolecular interactions experienced by complexes in a visual manner.

中文翻译：

多重氢键键合的三维超分子结构，由独特的三重互锁阴离子Zn（II）配位结构组成

通过溶剂热合成法获得了前所未有的三维多重氢键超分子骨架，该骨架包含互锁的三重自编织结构拓扑，该结构拓扑基于Zn（II）配位络合物的假石墨烯状无纺单层。。在这种超分子结构中产生了两个不同的大空腔。此外，对Hirshfeld表面分析的研究重现了X射线晶体结构分析的结果，并以可视的方式阐述了配合物经历的分子间相互作用。

更新日期：2020-03-30

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