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Eosin Y-catalyzed one-pot synthesis of spiro[4H-pyran-oxindole] under visible light irradiation
Tetrahedron ( IF 2.1 ) Pub Date : 2020-02-25 , DOI: 10.1016/j.tet.2020.131059 Meng-Nan Chen , Jia-Qi Di , Jiao-Mian Li , Li-Ping Mo , Zhan-Hui Zhang
中文翻译:
曙红Y催化可见光下一锅合成螺[4 H-吡喃-羟吲哚]
更新日期:2020-02-25
Tetrahedron ( IF 2.1 ) Pub Date : 2020-02-25 , DOI: 10.1016/j.tet.2020.131059 Meng-Nan Chen , Jia-Qi Di , Jiao-Mian Li , Li-Ping Mo , Zhan-Hui Zhang
An efficient and simple synthetic approach has been developed for the preparation of biologically interesting spiro[oxindole-3,4'-(4′H-pyran)] derivatives via visible light-mediated one-pot, three-component reaction of isatins, 1,3-dicarbonyl compounds and malononitrile by using an inexpensive organic dye, Na2 eosin Y, as the photocatalyst in aqueous ethyl lactate at ambient temperature. The substrate scope of this three-component reaction is expanded to linear 1,3-dicarbonyl compounds as viable starting materials. All rights reserved.
中文翻译:
曙红Y催化可见光下一锅合成螺[4 H-吡喃-羟吲哚]
一种高效和简单的合成方法已被开发用于生物有趣螺的制备[羟吲哚3,4' - (4' ħ吡喃)]通过可见光介导的单罐,靛红的三组分反应衍生物,1-在环境温度下,使用廉价的有机染料Na 2曙红Y作为光催化剂,在乳酸乙酯水溶液中制备1,3-二羰基化合物和丙二腈。这种三组分反应的底物范围扩大到线性1,3-二羰基化合物作为可行的起始原料。版权所有。