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Synthesis of 2,4-Diarylquinoline Derivatives via Chloranil-Promoted Oxidative Annulation and One-Pot Reaction
Synthesis ( IF 2.6 ) Pub Date : 2020-02-24 , DOI: 10.1055/s-0039-1691740 Dongping Cheng 1 , Xiaoliang Xu 2 , Jizhong Yan 1 , Xianhang Yan 1 , Jing Shen 1 , Yueqi Pu 1
Synthesis ( IF 2.6 ) Pub Date : 2020-02-24 , DOI: 10.1055/s-0039-1691740 Dongping Cheng 1 , Xiaoliang Xu 2 , Jizhong Yan 1 , Xianhang Yan 1 , Jing Shen 1 , Yueqi Pu 1
Affiliation
An oxidative annulation for the synthesis of 2,4-diarylquinolines from o-allylanilines is disclosed that uses recyclable reagent Chloranil as the oxidant. The corresponding products are obtained in moderate to excellent yields. Furthermore, a one-pot access to 2,4-diarylquinolines from easily available anilines and 1,3-diarylpropenes is described as a highly atom-efficient protocol that involves oxidative coupling, rearrangement, and oxidative annulation.
中文翻译:
氯腈促进的氧化环化和一锅法合成2,4-二芳基喹啉衍生物
公开了一种由邻烯丙基苯胺合成2,4-二芳基喹啉的氧化环合反应,该方法使用可循环利用的试剂氯腈作为氧化剂。以中等至优异的产率获得相应的产物。此外,从容易获得的苯胺和1,3-二芳基丙烯一锅通到2,4-二芳基喹啉被描述为一种高度原子有效的方案,涉及氧化偶联,重排和氧化环化。
更新日期:2020-02-24
中文翻译:
氯腈促进的氧化环化和一锅法合成2,4-二芳基喹啉衍生物
公开了一种由邻烯丙基苯胺合成2,4-二芳基喹啉的氧化环合反应,该方法使用可循环利用的试剂氯腈作为氧化剂。以中等至优异的产率获得相应的产物。此外,从容易获得的苯胺和1,3-二芳基丙烯一锅通到2,4-二芳基喹啉被描述为一种高度原子有效的方案,涉及氧化偶联,重排和氧化环化。