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Reference Correlations for the Viscosity of Molten LiF-NaF-KF, LiF-BeF2, and Li2CO3-Na2CO3-K2CO3
Journal of Physical and Chemical Reference Data ( IF 4.4 ) Pub Date : 2019-12-01 , DOI: 10.1063/1.5131349
K. Α. Tasidou 1 , J. Magnusson 2 , T. Munro 2 , M. J. Assael 1
Affiliation  

In 1974, reference correlations for the viscosity of molten LiF-NaF-KF, LiF-BeF2, and Li2CO3-Na2CO3-K2CO3 were proposed by Janz and have been extensively used since then. However, in the last 45 years, many additional measurements have been published. This is why in this paper, new reference correlations for the viscosity of these salts are proposed. All available experimental data for the viscosity of these three molten salts have been critically examined with the intention of establishing improved or new reference viscosity correlations. All experimental data have been categorized into primary and secondary data according to the quality of measurement specified by a series of criteria. The reference correlation proposed for LiF-NaF-KF, with an uncertainty of 2.9% at the 95% confidence level, expands the temperature range of the previous correlation from (770–970) K to (732–1163) K and retains its uncertainty. The correlation proposed for LiF-BeF2, with an uncertainty of 4.9% at the 95% confidence level, expands the high temperature range of the previous correlation from (740–870) K to (793–1573) K, with a slight loss in its uncertainty. It is, however, a much better correlation as it is based upon measurements not available at the time of the previous one. Finally, the reference correlation for Li2CO3-Na2CO3-K2CO3, with an uncertainty of 3%, also expands the temperature range of the previous correlation from (920–1170) K to (738–1170) K and retains its uncertainty.In 1974, reference correlations for the viscosity of molten LiF-NaF-KF, LiF-BeF2, and Li2CO3-Na2CO3-K2CO3 were proposed by Janz and have been extensively used since then. However, in the last 45 years, many additional measurements have been published. This is why in this paper, new reference correlations for the viscosity of these salts are proposed. All available experimental data for the viscosity of these three molten salts have been critically examined with the intention of establishing improved or new reference viscosity correlations. All experimental data have been categorized into primary and secondary data according to the quality of measurement specified by a series of criteria. The reference correlation proposed for LiF-NaF-KF, with an uncertainty of 2.9% at the 95% confidence level, expands the temperature range of the previous correlation from (770–970) K to (732–1163) K and retains its uncertainty. The correlation proposed for LiF-BeF2, with an uncertainty of 4.9% at the 95% confidence level,...

中文翻译:

熔融 LiF-NaF-KF、LiF-BeF2 和 Li2CO3-Na2CO3-K2CO3 粘度的参考相关性

1974 年,Janz 提出了熔融 LiF-NaF-KF、LiF-BeF2 和 Li2CO3-Na2CO3-K2CO3 粘度的参考关系式,并从那时起得到广泛应用。然而,在过去的 45 年中,已经发表了许多其他测量结果。这就是为什么在本文中,提出了这些盐的粘度的新参考相关性。这三种熔盐的粘度的所有可用实验数据都经过严格检查,目的是建立改进的或新的参考粘度相关性。根据一系列标准规定的测量质量,将所有实验数据分为初级数据和次级数据。为 LiF-NaF-KF 提出的参考相关性,在 95% 置信水平下的不确定性为 2.9%,将先前相关性的温度范围从 (770–970) K 扩展到 (732–1163) K 并保留其不确定性。为 LiF-BeF2 提出的相关性在 95% 的置信水平下具有 4.9% 的不确定性,将先前相关性的高温范围从 (740–870) K 扩展到 (793–1573) K,但在它的不确定性。然而,它是一种更好的相关性,因为它基于上一次测量时不可用的测量结果。最后,Li2CO3-Na2CO3-K2CO3 的参考相关性,不确定度为 3%,也将先前相关性的温度范围从 (920-1170) K 扩展到 (738-1170) K 并保留其不确定性。 1974 年, Janz 提出了熔融 LiF-NaF-KF、LiF-BeF2 和 Li2CO3-Na2CO3-K2CO3 粘度的参考相关性,并从那时起被广泛使用。然而,在过去的 45 年中,已经发表了许多其他测量结果。这就是为什么在本文中,提出了这些盐的粘度的新参考相关性。这三种熔盐的粘度的所有可用实验数据都经过严格检查,目的是建立改进的或新的参考粘度相关性。根据一系列标准规定的测量质量,将所有实验数据分为初级数据和次级数据。为 LiF-NaF-KF 提出的参考相关性在 95% 置信水平下的不确定性为 2.9%,将先前相关性的温度范围从 (770–970) K 扩展到 (732–1163) K 并保留其不确定性. 为 LiF-BeF2 提出的相关性,在 95% 置信水平下具有 4.9% 的不确定性,... 在过去的 45 年中,发表了许多其他测量结果。这就是为什么在本文中,提出了这些盐的粘度的新参考相关性。这三种熔盐的粘度的所有可用实验数据都经过严格检查,目的是建立改进的或新的参考粘度相关性。根据一系列标准规定的测量质量,将所有实验数据分为初级数据和次级数据。为 LiF-NaF-KF 提出的参考相关性在 95% 置信水平下的不确定性为 2.9%,将先前相关性的温度范围从 (770–970) K 扩展到 (732–1163) K 并保留其不确定性. 为 LiF-BeF2 提出的相关性,在 95% 置信水平下具有 4.9% 的不确定性,... 在过去的 45 年中,发表了许多其他测量结果。这就是为什么在本文中,提出了这些盐的粘度的新参考相关性。这三种熔盐的粘度的所有可用实验数据都经过严格检查,目的是建立改进的或新的参考粘度相关性。根据一系列标准规定的测量质量,将所有实验数据分为初级数据和次级数据。为 LiF-NaF-KF 提出的参考相关性在 95% 置信水平下的不确定性为 2.9%,将先前相关性的温度范围从 (770–970) K 扩展到 (732–1163) K 并保留其不确定性. 为 LiF-BeF2 提出的相关性,在 95% 置信水平下具有 4.9% 的不确定性,...
更新日期:2019-12-01
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