Application of metal free aromatization to total synthesis of perlolyrin, flazin, eudistomin U and harmane,Journal of Heterocyclic Chemistry

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Application of metal free aromatization to total synthesis of perlolyrin, flazin, eudistomin U and harmane
Journal of Heterocyclic Chemistry ( IF 2.0 ) Pub Date : 2020-02-24 , DOI: 10.1002/jhet.3931
Srinath Santhanam ₁ , Abinaya Ramu ₁ , Baskar Baburaj ₁ , Balasubramanian Kalpatu Kuppusamy ₂

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Application of our recently reported metal free reaction conditions to the total synthesis of the four different and selective biologically interesting β‐carboline natural products is reported. Using this simple methodology, flazin, perlolyrine, eudistomin U and harmane containing heteroaryl and alkyl substituents at C1 position were synthesized in good yields.

中文翻译：

无金属芳构化技术在全合成水杨素，flazin，eudistomin U和harmane中的应用

据报道，我们最近报道的无金属反应条件在四种不同的，具有选择性的生物学意义上的β-咔啉天然产物的全合成中的应用。使用这种简单的方法，以高收率合成了在C1位置含有杂芳基和烷基取代基的flazin，perlolyrine，eudistomin U和harmane。

更新日期：2020-02-24

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