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Influence of exfoliated graphite inclusion on the thermal, mechanical, dielectric and solvent transport characteristics of fluoroelastomer nanocomposites
Journal of Polymer Research ( IF 2.6 ) Pub Date : 2020-02-24 , DOI: 10.1007/s10965-020-2040-x
Grace Moni , Thomasukutty Jose , Sreelakshmi Rajeevan , Anshidha Mayeen , Alphy Rejimon , P. S. Sarath , Soney C. George

Nanocomposites with multifunctional properties are of great interest as they meet the needs of the developing industrial and engineering fields. The present study focus on the development of multifunctional elastomeric nanocomposites with exfoliated graphite (EG) as the reinforcing content and the speciality material fluoroelastomer as the polymer matrix. Morphological analysis of the nanocomposites in terms of TEM, AFM and SEM were done to look at the polymer-filler interactions which in turn lead to the property enhancement. The dispersion of the EG in the nanoscale which resulted in the property enhancement is clear from the TEM images. Nanocomposites exhibited improved thermal stability and higher mechanical strength by the addition of 12 phr of EG nanofiller. Moreover the dielectric performance of the nanocomposites was also enhanced by the addition of conductive EG nanofiller and the nanocomposites showed higher dielectric constant value and AC conductivity with lower dielectric loss. In addition to this the solvent transport features of the nanocomposites were also analyzed to reveal the reinforcement effect of the nanofiller and the effective polymer-filler interactions.



中文翻译:

剥落的石墨夹杂物对含氟弹性体纳米复合材料的热,机械,介电和溶剂传输特性的影响

具有多功能性质的纳米复合材料满足了发展中的工业和工程领域的需求,因此引起了极大的兴趣。本研究的重点是开发以剥落石墨(EG)为增强成分和特种材料含氟弹性体为聚合物基质的多功能弹性体纳米复合材料。根据TEM,AFM和SEM对纳米复合材料进行了形态分析,以研究聚合物与填料之间的相互作用,进而提高了性能。从TEM图像中可以清楚地看出EG在纳米级中的分散,其导致性能增强。通过添加12 phr EG纳米填料,纳米复合材料表现出改善的热稳定性和更高的机械强度。此外,通过添加导电EG纳米填料还增强了纳米复合材料的介电性能,并且纳米复合材料显示出较高的介电常数值和AC电导率,且介电损耗较低。除此之外,还分析了纳米复合材料的溶剂传输特征,以揭示纳米填料的增强作用和有效的聚合物-填料相互作用。

更新日期:2020-02-24
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