Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand.,Chemical Communications

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Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand.
Chemical Communications ( IF 4.3 ) Pub Date : 2020/02/24 , DOI: 10.1039/d0cc00933d
Daisuke Shimoyama ₁ , Ryo Sekiya ₁ , Takeharu Haino ₁

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An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise to upper-rim-functionalized biscavitands that self-assembled to form a supramolecular polymer in the solid state.

中文翻译：

脚到脚连接的biscavitand的上边缘官能化和超分子聚合。

通过芳族Finkelstein碘化反应以高收率合成了octaiodobiscavitand。octaiodobiscavitand的Sonogashira和Suzuki偶联反应产生了上边缘官能化的biscavitands，它们自组装形成固态的超分子聚合物。

更新日期：2020-03-31

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