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Heterogeneous Photocatalysis in Organic Synthesis
ChemPhotoChem ( IF 3.0 ) Pub Date : 2020-03-23 , DOI: 10.1002/cptc.202000014 Sebastian Gisbertz 1, 2 , Bartholomäus Pieber 1
ChemPhotoChem ( IF 3.0 ) Pub Date : 2020-03-23 , DOI: 10.1002/cptc.202000014 Sebastian Gisbertz 1, 2 , Bartholomäus Pieber 1
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Visible light photocatalysis relies mainly on expensive noble metal complexes and organic dyes that are not recyclable. Heterogeneous semiconductors, which are mainly applied for artificial photosynthesis and wastewater treatment, are a promising sustainable alternative and gain increasing attention. Inorganic and organic semiconductors with suitable bandgaps are among the most widely studied heterogeneous photocatalysts due to their high stability and recyclability. More recently, microporous materials, such as conjugated organic polymers, covalent organic frameworks, and metal organic frameworks that can be tuned and designed on a molecular level showed promising results. This review provides an overview of the most common heterogeneous photocatalysts with a focus on their applicability in organic synthesis.
中文翻译：
有机合成中的非均相光催化
可见光光催化主要依靠昂贵的贵金属络合物和不可回收的有机染料。主要用于人工光合作用和废水处理的异质半导体是一种有前途的可持续替代方法，受到越来越多的关注。具有合适带隙的无机和有机半导体由于其高稳定性和可回收性而成为研究最广泛的多相光催化剂之一。最近，可以在分子水平上调节和设计的微孔材料，例如共轭有机聚合物，共价有机骨架和金属有机骨架，显示出令人鼓舞的结果。这篇综述概述了最常见的多相光催化剂，重点是它们在有机合成中的适用性。
更新日期：2020-03-23
中文翻译：
有机合成中的非均相光催化
可见光光催化主要依靠昂贵的贵金属络合物和不可回收的有机染料。主要用于人工光合作用和废水处理的异质半导体是一种有前途的可持续替代方法，受到越来越多的关注。具有合适带隙的无机和有机半导体由于其高稳定性和可回收性而成为研究最广泛的多相光催化剂之一。最近，可以在分子水平上调节和设计的微孔材料，例如共轭有机聚合物，共价有机骨架和金属有机骨架，显示出令人鼓舞的结果。这篇综述概述了最常见的多相光催化剂，重点是它们在有机合成中的适用性。
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